AustralieFrV1, Main, Exploration, bibRecord, 007111

Cluster control in oligouranyl complexes of p-t-butylcalix[8]arene

Identifieur interne : 007111 ( Main/Exploration ); précédent : 007110; suivant : 007112

Cluster control in oligouranyl complexes of p-t-butylcalix[8]arene

Auteurs : Jack M. Harrowfield [France] ; Mark I. Ogden [Australie] ; Brian W. Skelton [Australie] ; Allan H. White [Australie]

Source :

Dalton Transactions [ 1477-9226 ] ; 2010.

RBID : ISTEX:FD9D465A978C9981ADCDD000992D78C72A333585

English descriptors

KwdEn :
- Acetonitrile, Analytical correction, Anion, Aromatic rings, Asymmetric unit, Calixarene, Calixarene anions, Calixarene conformation, Calixarene ligand, Calixarenes, Cation, Central oxygen atom, Chem, Conformation, Convergent atoms, Crystallographic symmetry, Dalton trans, Diffraction studies, Diuranate, Divergent atoms, Dmso solution, Equatorial, Equatorial plane, Hydrogen atoms, Initial reaction mixture, Lewis base, Ligand, Metal ions, Mirror plane, Oxygen atoms, Pentagonal bipyramidal, Phenolic oxygen atoms, Present examples, Present work, Protonation state, Ring size, Rint, Royal society, Same side, Solvent components, Solvent molecules, Space group, Structure determinations, Tetramethylammonium hydroxide, Thermal ellipsoids, Trans, Triethylammonium salt, Uranium atoms, Uranyl, Uranyl units.
Teeft :
- Acetonitrile, Analytical correction, Anion, Aromatic rings, Asymmetric unit, Calixarene, Calixarene anions, Calixarene conformation, Calixarene ligand, Calixarenes, Cation, Central oxygen atom, Chem, Conformation, Convergent atoms, Crystallographic symmetry, Dalton trans, Diffraction studies, Diuranate, Divergent atoms, Dmso solution, Equatorial, Equatorial plane, Hydrogen atoms, Initial reaction mixture, Lewis base, Ligand, Metal ions, Mirror plane, Oxygen atoms, Pentagonal bipyramidal, Phenolic oxygen atoms, Present examples, Present work, Protonation state, Ring size, Rint, Royal society, Same side, Solvent components, Solvent molecules, Space group, Structure determinations, Tetramethylammonium hydroxide, Thermal ellipsoids, Trans, Triethylammonium salt, Uranium atoms, Uranyl, Uranyl units.

Abstract

Formation of uranyl ion complexes of p-t-butylcalix[8]arene by reaction of the calixarene with [UO2(dmso)5]2+ in the presence of various bases leads to the crystallisation of solids with interestingly different stoichiometry, involving both di- and tri-uranate oligomers bound to the calixarene in anionic species. In all, the calixarene hexa-anion is present in a virtually identical conformation, suggesting that conformational preferences of the ligand must be a major factor controlling the form of the bound oxo-metal complex. Hydrogen bonding to the anions does not appear to be prominent even in the presence of protonated amines and this may explain the formation of some remarkable cation/solvent/simple anion clusters found within the lattices.

Url:

https://api.istex.fr/document/FD9D465A978C9981ADCDD000992D78C72A333585/fulltext/pdf

DOI: 10.1039/c0dt00667j

Affiliations:

Links toward previous steps (curation, corpus...)

to stream Istex, to step Corpus: 002F85
to stream Istex, to step Curation: 002F85
to stream Istex, to step Checkpoint: 000A22
to stream Main, to step Merge: 007645
to stream Main, to step Curation: 007111

Le document en format XML

<record><TEI wicri:istexFullTextTei="biblStruct"><teiHeader><fileDesc><titleStmt><title>Cluster control in oligouranyl complexes of p-t-butylcalix[8]arene</title>
<author wicri:is="90%"><name sortKey="Harrowfield, Jack M" sort="Harrowfield, Jack M" uniqKey="Harrowfield J" first="Jack M." last="Harrowfield">Jack M. Harrowfield</name>
</author>
<author wicri:is="90%"><name sortKey="Ogden, Mark I" sort="Ogden, Mark I" uniqKey="Ogden M" first="Mark I." last="Ogden">Mark I. Ogden</name>
</author>
<author wicri:is="90%"><name sortKey="Skelton, Brian W" sort="Skelton, Brian W" uniqKey="Skelton B" first="Brian W." last="Skelton">Brian W. Skelton</name>
</author>
<author wicri:is="90%"><name sortKey="White, Allan H" sort="White, Allan H" uniqKey="White A" first="Allan H." last="White">Allan H. White</name>
</author>
</titleStmt>
<publicationStmt><idno type="wicri:source">ISTEX</idno>
<idno type="RBID">ISTEX:FD9D465A978C9981ADCDD000992D78C72A333585</idno>
<date when="2010" year="2010">2010</date>
<idno type="doi">10.1039/c0dt00667j</idno>
<idno type="url">https://api.istex.fr/document/FD9D465A978C9981ADCDD000992D78C72A333585/fulltext/pdf</idno>
<idno type="wicri:Area/Istex/Corpus">002F85</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Corpus" wicri:corpus="ISTEX">002F85</idno>
<idno type="wicri:Area/Istex/Curation">002F85</idno>
<idno type="wicri:Area/Istex/Checkpoint">000A22</idno>
<idno type="wicri:explorRef" wicri:stream="Istex" wicri:step="Checkpoint">000A22</idno>
<idno type="wicri:doubleKey">1477-9226:2010:Harrowfield J:cluster:control:in</idno>
<idno type="wicri:Area/Main/Merge">007645</idno>
<idno type="wicri:Area/Main/Curation">007111</idno>
<idno type="wicri:Area/Main/Exploration">007111</idno>
</publicationStmt>
<sourceDesc><biblStruct><analytic><title level="a">Cluster control in oligouranyl complexes of p-t-butylcalix[8]arene</title>
<author wicri:is="90%"><name sortKey="Harrowfield, Jack M" sort="Harrowfield, Jack M" uniqKey="Harrowfield J" first="Jack M." last="Harrowfield">Jack M. Harrowfield</name>
<affiliation wicri:level="3"><country xml:lang="fr">France</country>
<wicri:regionArea>Institut de Science et d'Ingnierie Supramolculaires, Universit de Strasbourg, 67083, Strasbourg</wicri:regionArea>
<placeName><region type="region" nuts="2">Grand Est</region>
<region type="old region" nuts="2">Alsace (région administrative)</region>
<settlement type="city">Strasbourg</settlement>
</placeName>
</affiliation>
</author>
<author wicri:is="90%"><name sortKey="Ogden, Mark I" sort="Ogden, Mark I" uniqKey="Ogden M" first="Mark I." last="Ogden">Mark I. Ogden</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>Department of Chemistry and Nanochemistry Research Institute, Curtin University of Technology, 6845, GPO Box U 1987, WA, Perth</wicri:regionArea>
<wicri:noRegion>Perth</wicri:noRegion>
</affiliation>
<affiliation wicri:level="1"><country wicri:rule="url">Australie</country>
</affiliation>
</author>
<author wicri:is="90%"><name sortKey="Skelton, Brian W" sort="Skelton, Brian W" uniqKey="Skelton B" first="Brian W." last="Skelton">Brian W. Skelton</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>Chemistry M313, School of Biomedical and Chemical Sciences, University of Western Australia, 6009, WA, Crawley</wicri:regionArea>
<wicri:noRegion>Crawley</wicri:noRegion>
</affiliation>
</author>
<author wicri:is="90%"><name sortKey="White, Allan H" sort="White, Allan H" uniqKey="White A" first="Allan H." last="White">Allan H. White</name>
<affiliation wicri:level="1"><country xml:lang="fr">Australie</country>
<wicri:regionArea>Chemistry M313, School of Biomedical and Chemical Sciences, University of Western Australia, 6009, WA, Crawley</wicri:regionArea>
<wicri:noRegion>Crawley</wicri:noRegion>
</affiliation>
</author>
</analytic>
<monogr></monogr>
<series><title level="j">Dalton Transactions</title>
<title level="j" type="abbrev">Dalton Trans.</title>
<idno type="ISSN">1477-9226</idno>
<idno type="eISSN">1477-9234</idno>
<imprint><publisher>The Royal Society of Chemistry.</publisher>
<date type="published" when="2010">2010</date>
<biblScope unit="volume">39</biblScope>
<biblScope unit="issue">35</biblScope>
<biblScope unit="page" from="8313">8313</biblScope>
<biblScope unit="page" to="8318">8318</biblScope>
</imprint>
<idno type="ISSN">1477-9226</idno>
</series>
</biblStruct>
</sourceDesc>
<seriesStmt><idno type="ISSN">1477-9226</idno>
</seriesStmt>
</fileDesc>
<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Acetonitrile</term>
<term>Analytical correction</term>
<term>Anion</term>
<term>Aromatic rings</term>
<term>Asymmetric unit</term>
<term>Calixarene</term>
<term>Calixarene anions</term>
<term>Calixarene conformation</term>
<term>Calixarene ligand</term>
<term>Calixarenes</term>
<term>Cation</term>
<term>Central oxygen atom</term>
<term>Chem</term>
<term>Conformation</term>
<term>Convergent atoms</term>
<term>Crystallographic symmetry</term>
<term>Dalton trans</term>
<term>Diffraction studies</term>
<term>Diuranate</term>
<term>Divergent atoms</term>
<term>Dmso solution</term>
<term>Equatorial</term>
<term>Equatorial plane</term>
<term>Hydrogen atoms</term>
<term>Initial reaction mixture</term>
<term>Lewis base</term>
<term>Ligand</term>
<term>Metal ions</term>
<term>Mirror plane</term>
<term>Oxygen atoms</term>
<term>Pentagonal bipyramidal</term>
<term>Phenolic oxygen atoms</term>
<term>Present examples</term>
<term>Present work</term>
<term>Protonation state</term>
<term>Ring size</term>
<term>Rint</term>
<term>Royal society</term>
<term>Same side</term>
<term>Solvent components</term>
<term>Solvent molecules</term>
<term>Space group</term>
<term>Structure determinations</term>
<term>Tetramethylammonium hydroxide</term>
<term>Thermal ellipsoids</term>
<term>Trans</term>
<term>Triethylammonium salt</term>
<term>Uranium atoms</term>
<term>Uranyl</term>
<term>Uranyl units</term>
</keywords>
<keywords scheme="Teeft" xml:lang="en"><term>Acetonitrile</term>
<term>Analytical correction</term>
<term>Anion</term>
<term>Aromatic rings</term>
<term>Asymmetric unit</term>
<term>Calixarene</term>
<term>Calixarene anions</term>
<term>Calixarene conformation</term>
<term>Calixarene ligand</term>
<term>Calixarenes</term>
<term>Cation</term>
<term>Central oxygen atom</term>
<term>Chem</term>
<term>Conformation</term>
<term>Convergent atoms</term>
<term>Crystallographic symmetry</term>
<term>Dalton trans</term>
<term>Diffraction studies</term>
<term>Diuranate</term>
<term>Divergent atoms</term>
<term>Dmso solution</term>
<term>Equatorial</term>
<term>Equatorial plane</term>
<term>Hydrogen atoms</term>
<term>Initial reaction mixture</term>
<term>Lewis base</term>
<term>Ligand</term>
<term>Metal ions</term>
<term>Mirror plane</term>
<term>Oxygen atoms</term>
<term>Pentagonal bipyramidal</term>
<term>Phenolic oxygen atoms</term>
<term>Present examples</term>
<term>Present work</term>
<term>Protonation state</term>
<term>Ring size</term>
<term>Rint</term>
<term>Royal society</term>
<term>Same side</term>
<term>Solvent components</term>
<term>Solvent molecules</term>
<term>Space group</term>
<term>Structure determinations</term>
<term>Tetramethylammonium hydroxide</term>
<term>Thermal ellipsoids</term>
<term>Trans</term>
<term>Triethylammonium salt</term>
<term>Uranium atoms</term>
<term>Uranyl</term>
<term>Uranyl units</term>
</keywords>
</textClass>
<langUsage><language ident="en">en</language>
</langUsage>
</profileDesc>
</teiHeader>
<front><div type="abstract">Formation of uranyl ion complexes of p-t-butylcalix[8]arene by reaction of the calixarene with [UO2(dmso)5]2+ in the presence of various bases leads to the crystallisation of solids with interestingly different stoichiometry, involving both di- and tri-uranate oligomers bound to the calixarene in anionic species. In all, the calixarene hexa-anion is present in a virtually identical conformation, suggesting that conformational preferences of the ligand must be a major factor controlling the form of the bound oxo-metal complex. Hydrogen bonding to the anions does not appear to be prominent even in the presence of protonated amines and this may explain the formation of some remarkable cation/solvent/simple anion clusters found within the lattices.</div>
</front>
</TEI>
<affiliations><list><country><li>Australie</li>
<li>France</li>
</country>
<region><li>Alsace (région administrative)</li>
<li>Grand Est</li>
</region>
<settlement><li>Strasbourg</li>
</settlement>
</list>
<tree><country name="France"><region name="Grand Est"><name sortKey="Harrowfield, Jack M" sort="Harrowfield, Jack M" uniqKey="Harrowfield J" first="Jack M." last="Harrowfield">Jack M. Harrowfield</name>
</region>
</country>
<country name="Australie"><noRegion><name sortKey="Ogden, Mark I" sort="Ogden, Mark I" uniqKey="Ogden M" first="Mark I." last="Ogden">Mark I. Ogden</name>
</noRegion>
<name sortKey="Ogden, Mark I" sort="Ogden, Mark I" uniqKey="Ogden M" first="Mark I." last="Ogden">Mark I. Ogden</name>
<name sortKey="Skelton, Brian W" sort="Skelton, Brian W" uniqKey="Skelton B" first="Brian W." last="Skelton">Brian W. Skelton</name>
<name sortKey="White, Allan H" sort="White, Allan H" uniqKey="White A" first="Allan H." last="White">Allan H. White</name>
</country>
</tree>
</affiliations>
</record>

Pour manipuler ce document sous Unix (Dilib)

EXPLOR_STEP=$WICRI_ROOT/Wicri/Asie/explor/AustralieFrV1/Data/Main/Exploration

HfdSelect -h $EXPLOR_STEP/biblio.hfd -nk 007111 | SxmlIndent | more

HfdSelect -h $EXPLOR_AREA/Data/Main/Exploration/biblio.hfd -nk 007111 | SxmlIndent | more

Pour mettre un lien sur cette page dans le réseau Wicri

{{Explor lien
   |wiki=    Wicri/Asie
   |area=    AustralieFrV1
   |flux=    Main
   |étape=   Exploration
   |type=    RBID
   |clé=     ISTEX:FD9D465A978C9981ADCDD000992D78C72A333585
   |texte=   Cluster control in oligouranyl complexes of p-t-butylcalix[8]arene
}}

This area was generated with Dilib version V0.6.33.
Data generation: Tue Dec 5 10:43:12 2017. Site generation: Tue Mar 5 14:07:20 2024

	Serveur d'exploration sur les relations entre la France et l'Australie
	Attention, ce site est en cours de développement ! Attention, site généré par des moyens informatiques à partir de corpus bruts. Les informations ne sont donc pas validées.

Serveur d'exploration sur les relations entre la France et l'Australie

Cluster control in oligouranyl complexes of p-t-butylcalix[8]arene

Cluster control in oligouranyl complexes of p-t-butylcalix[8]arene

Source :

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri